全文获取类型
收费全文 | 30901篇 |
免费 | 3664篇 |
国内免费 | 1823篇 |
专业分类
电工技术 | 1381篇 |
技术理论 | 5篇 |
综合类 | 2035篇 |
化学工业 | 8579篇 |
金属工艺 | 1408篇 |
机械仪表 | 996篇 |
建筑科学 | 1598篇 |
矿业工程 | 1216篇 |
能源动力 | 2314篇 |
轻工业 | 2046篇 |
水利工程 | 637篇 |
石油天然气 | 2170篇 |
武器工业 | 158篇 |
无线电 | 1415篇 |
一般工业技术 | 3294篇 |
冶金工业 | 2818篇 |
原子能技术 | 214篇 |
自动化技术 | 4104篇 |
出版年
2024年 | 58篇 |
2023年 | 676篇 |
2022年 | 978篇 |
2021年 | 1157篇 |
2020年 | 1239篇 |
2019年 | 1116篇 |
2018年 | 1011篇 |
2017年 | 1231篇 |
2016年 | 1302篇 |
2015年 | 1225篇 |
2014年 | 1950篇 |
2013年 | 2086篇 |
2012年 | 2365篇 |
2011年 | 2590篇 |
2010年 | 1931篇 |
2009年 | 1903篇 |
2008年 | 1777篇 |
2007年 | 1876篇 |
2006年 | 1676篇 |
2005年 | 1241篇 |
2004年 | 1057篇 |
2003年 | 899篇 |
2002年 | 753篇 |
2001年 | 650篇 |
2000年 | 558篇 |
1999年 | 495篇 |
1998年 | 413篇 |
1997年 | 325篇 |
1996年 | 326篇 |
1995年 | 237篇 |
1994年 | 253篇 |
1993年 | 190篇 |
1992年 | 185篇 |
1991年 | 132篇 |
1990年 | 78篇 |
1989年 | 72篇 |
1988年 | 53篇 |
1987年 | 35篇 |
1986年 | 40篇 |
1985年 | 51篇 |
1984年 | 38篇 |
1983年 | 38篇 |
1982年 | 29篇 |
1981年 | 23篇 |
1980年 | 19篇 |
1979年 | 10篇 |
1978年 | 6篇 |
1977年 | 6篇 |
1973年 | 5篇 |
1951年 | 9篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
51.
乡村产业中的化石能源设备逐渐被电能技术替代,引起了乡村负荷波动增大、部分时段产生集中高负荷的问题。为了解决以上问题,将低品位清洁能源应用至乡村的茶叶生产中,针对烘茶全过程的工艺要求提出了跨临界CO2热泵烘茶技术;并以某茶叶生产乡村为对象,对其代表台区的全年日用电量及产茶日负荷进行了分析,得出采用CO2热泵烘茶后其负荷得到大幅度削减,整体可降低至原负荷的39.6%~46.8%,峰值负荷与平时负荷的比值由原本的13.6降至5.4~6.2。跨临界CO2热泵应用至农产品生产中可有效缓解乡村供电压力。 相似文献
52.
《Ceramics International》2022,48(17):24471-24475
Al2O3–SiC composite powder (ASCP) was successfully synthesized using a novel molten-salt-assisted aluminum/carbothermal reduction (MS-ACTR) method with silica fume, aluminum powder, and carbon black as raw materials; NaCl–KCl was used as the molten salt medium. The effects of the synthesis temperature and salt-reactant ratio on the phase composition and microstructure were investigated. The results showed that the Al2O3–SiC content increased with an increase in molten salt temperature, and the salt–reactant ratio in the range of 1.5:1–2.5:1 had an impact on the fabrication of ASCP. The optimum condition for synthesizing ASCP from NaCl–KCl molten salt consisted of maintaining the temperature at 1573 K for 4 h. The chemical reaction thermodynamics and growth mechanism indicate that the molten salt plays an important role in the formation of SiC whiskers by following the vapor-solid growth mode in the MS-ACTR treatment. This study demonstrates that the addition of molten salt as a reaction medium is a promising approach for synthesizing high-melting-point composite powders at low temperatures. 相似文献
53.
《International Journal of Hydrogen Energy》2021,46(58):29812-29821
This study investigates the effect of two different iron compounds (zero-valent iron nanoparticle: nZVI and iron oxide nanoparticles: nIO) and pH on fermentative biohydrogen production from molasses-based distillery wastewater. The nZVI and nIO of optimum particle sizes of 50 nm and 55 nm respectively were synthesized and applied for fermentative hydrogen (H2) production. The addition of nIO & nZVI at (0.7 g/L, pH: 6) resulted in the highest H2 yield, H2 production rate, H2 content and COD reduction. Moreover, the kinetic parameters of H2 production potential (P) and H2 production rate (Rm) increased to 387 mL, and 22.2 mL/h, respectively for nZVI, these values were 363 mL and 21.8 mL/h for nIO. The results obtained indicated the positive effect of nZVI and nIO addition on enhanced fermentative H2 production. The addition of nZVI & nIO resulted in 71% and 69.4% enhancement in biohydrogen production respectively. 相似文献
54.
本实验以热烫面团为研究对象,通过凯氏定氮法、粒径分析、傅里叶变换红外光谱以及快速黏度分析等手段,研究55、65、75、85 ℃和95 ℃热烫温度下小麦面团中麦谷蛋白大聚体的质量分数、粒径分布、蛋白质二级结构以及面团中淀粉的糊化特性的变化情况。结果表明:随着热烫温度的升高,面团中麦谷蛋白大聚体质量分数呈现显著增大的趋势(P<0.05),小粒径的麦谷蛋白大聚体向中粒径和大粒径转变;面团中蛋白质二级结构发生变化,部分α-螺旋和β-折叠结构转变为β-转角和无规卷曲。同时,面团中淀粉的糊化度随着热烫温度的升高逐渐增大;淀粉的峰值黏度、最低黏度、衰减值、最终黏度、回生值和峰值时间均呈现出减小的趋势,在热烫温度高于75 ℃时,这种变化更加显著。 相似文献
55.
《International Journal of Hydrogen Energy》2021,46(55):28011-28020
Transition metal-based compounds, due to their excellent ORR catalytic performance under alkaline condition, have recently emerged as one of the most promising alternatives to noble metal-based ORR catalysts. It is worth noting that manganese oxide can take an unique advantage for decomposition of intermediate adsorption products H2O2 and can effectively reduce O2 to OH−. However, most research has focused on MnO2, while attention has rarely been paid to MnO catalysts. In addition, under high-temperature pyrolysis condition, MnO is the most stable manganese oxide but MnO nanoparticles easily agglomerate. Hence, it is very difficult to obtain well-dispersed and small-sized MnO nanoparticles. Herein, on the basis of pre-synthesizing uniformly distributed manganese complexes on the reduced graphene oxide (rGO), we innovatively prepare highly dispersed and small-sized MnO nanoparticles (~3.94 nm) via high-temperature pyrolysis, which are uniformly anchored on N-doped reduced graphene oxide (NrGO) as an efficient oxygen reduction electrocatalyst. The as-obtained MnO/NrGO (1050 °C) electrocatalyst achieves satisfactory onset potential (0.942 V) and half-wave potential (0.820 V) under alkaline condition. And the limiting current density is 4.17 mA cm−2, which is very close to that of Pt/C (20 wt%, JM). Meanwhile, MnO/NrGO (1050 °C) catalyst presents superior longstanding durability and methanol resistance than Pt/C (JM). This work indicates that high-temperature pyrolysis can improve the purity of manganese oxide, simultaneously the defects of NrGO can reduce particle size of MnO nanoparticles, which are greatly beneficial to improve ORR performance. This work provides a new idea for research of MnO catalysts for ORR in the future. 相似文献
56.
Yan Luo Zeming Tang Guiqiang Cao Da Bi David P. Trudgeon Adeline Loh Xiaohong Li Qingxue Lai Yanyu Liang 《International Journal of Hydrogen Energy》2021,46(2):1997-2006
Atomically dispersed transition metals anchored on N-doped carbon have been successfully developed as promising electrocatalysts for acidic oxygen reduction reaction (ORR). Nonetheless, how to introduce and construct single-atomic active sites is still a big challenge. Herein, a novel concave dodecahedron catalyst of N-doped carbon (FeCuNC) with well confined atomically dispersed bivalent Fe sites was facilely developed via a Cu-assisted induced strategy. The obtained catalyst delivered outstanding ORR performance in 0.5 M H2SO4 media with a half-wave potential (E1/2) of 0.82 V (vs reversible hydrogen electrode, RHE), stemming from the highly active bivalent Fe-Nx sites with sufficient exposure and accessibility guaranteed by the high specific surface area and curved surface. This work provides a simple but efficient metal-assisted induced strategy to tune the configurations of atomically dispersed active sites as well as microscopy structures of carbon matrix to develop promising PGM-free catalysts for proton exchange membrane fuel cell (PEMFC) applications. 相似文献
57.
Chunyu Zhang Guozhu Liu Bo Ning Shuairen Qian Danning Zheng Li Wang 《International Journal of Hydrogen Energy》2021,46(27):14277-14287
The electrochemical oxygen reduction reaction (ORR) via two-electron pathway is a sustainable way of producing hydrogen peroxide. Nanostructured carbon materials are proved to be effective catalysts for 2e? ORR. Herein, a series of mesoporous carbon with tunable nitrogen species and oxygen functional groups were synthesized by varying the added amount of dopamine hydrochloride as nitrogen and oxygen source. The modified catalysts exhibited higher content of pyrrolic-N and ether C–O groups which are confirmed by a series of characterization. Raman spectra and correlation analysis revealed that the increased proportion of defect sites in carbon materials are closely related to the introduced pyrrolic-N and ether C–O groups. And the rotating ring-disk electrode (RRDE) measurement carried out in 0.1 M KOH electrolyte showed the H2O2 selectivity increased with the content of defect sites. Among them, the optimized catalyst (NOC-6M) exhibited a selectivity of 95.2% and a potential of 0.71 V vs. RHE at ?1 mA cm?2. Moreover, NOC-6M possessed the high H2O2 production rate of 548.8 mmol gcat?1 h?1 with faradaic efficiency of 92.4% in a two-chamber H-cell. Further mechanistic analysis revealed that the introduction of pyrrolic-N and ether C–O are likely to improve the binding energy of the defect sites toward 1OOH intermediate, resulting in a more favorable 2e? ORR pathway for H2O2 production. 相似文献
58.
Deok-Hye Park Yo-Seob Kim Sang-Beom Han Woo-Jun Lee Hak-Joo Lee Yong-Soo Lee Sang-Hyun Moon Kyung-Won Park 《International Journal of Hydrogen Energy》2021,46(43):22499-22507
Electrochemical reactions such as the oxygen evolution reaction (OER), oxygen reduction reaction (ORR), and methanol oxidation reaction (MOR) are essential for energy conversion applications such as water electrolysis and fuel cells. Furthermore, Pt or Ir-related materials have been extensively utilized as electrocatalysts for the OER, ORR, and MOR. To reduce the utilization of precious metals, innovative catalyst structures should be proposed. Herein, we report a bi-metallic phosphide (Ni2P and PdP2) structure surrounded by graphitic carbon (Ni–Pd–P/C) with an enhanced electrochemical activity as compared to conventional electrocatalysts. Despite the low Pd content of 3 at%, Ni–Pd–P/C exhibits a low overpotential of 330 mV at 10 mA cm?2 in the OER, high specific activity (2.82 mA cm?2 at 0.8 V) for the ORR, and a high current density of 1.101 A mg?1 for the MOR. The superior electrochemical performance of Ni–Pd–P/C may be attributed to the synergistic effect of the bi-metallic phosphide structure and core-shell structure formed by graphitic carbon. 相似文献
59.
Meifang Luo Chaozhong Guo Xinyi Luo Zhaoxu Li Yuan Qin Weizhong Zhang 《International Journal of Hydrogen Energy》2021,46(2):2117-2127
It is of great urgency to design inexpensive and high-performance oxygen reduction reaction (ORR) electrocatalysts derived from biowastes as substitutes for Pt-based materials in electrochemical energy-conversion devices. Here we propose a strategy to synthesize three-dimensional (3D) porous nitrogen-doped network carbons to catalyze the ORR from two-step pyrolysis engineering of biowaste scale combined with the use of a ZnCl2 activator and a FeCl2 promotor. Electrochemical tests show that the synthesized network carbons have exhibited comparable ORR catalytic activity with a half-wave potential (~0.85 V vs. RHE) and outstanding cyclical stability in comparison to the Pt/C catalyst. Beyond that, a high electron transfer number (~3.8) and a low peroxide yield (<7.6%) can be obtained, indicating a four-electron reaction pathway. The maximum power density is ~68 mW cm?2, but continuous discharge curves (at a constant potential of ~1.30 V) for 12 h are not obviously declined in Zn-air battery tests using synthesized network carbons as the cathodic catalyst. The formation of 3D porous structures with high BET surface area can effectively expose the surface catalytic sites and promote mass transportation to boost the ORR activity. This work may open a new idea to prepare porous carbon-based catalysts for some important reactions in new energy devices. 相似文献
60.
Hehuan Cao Jidong Cao Fanghui Wang Shuxian Di Hong Zhu Min Pu Andzhela Bulanova 《International Journal of Hydrogen Energy》2021,46(35):18284-18293
To accelerate the commercialization of fuel cells, many efforts have been made to develope highly active and durable Pt-based catalyst for oxygen reduction reaction (ORR). Herein, PtCu porous nanowires (PNWs) with controllable composition are synthesized through an ultrasound-assisted galvanic replacement reaction. The porous structure, surface strain, and electronic property of PtCu PNWs are optimized by tuning composition, which can improve activity for ORR. Electrochemical tests reveal that the mass activity of Pt0.5Cu0.5 PNWs (Pt/Cu atomic ratio of 1:1) reaches 0.80 A mgPt?1, which is about 5 times higher than that of the commercial Pt/C catalyst. Notably, the improved activity of the porous nanowire catalyst is also confirmed in the single-cell test. In addition, the large contact area with the carrier and internal interconnection structure of Pt0.5Cu0.5 PNWs enables them to exhibit much better durability than the commercial Pt/C catalyst and Pt0.5Cu0.5 nanotubes in accelerated durability test. 相似文献